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1,4-Phenylenediamine

1,4-Phenylenediamine MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

SDS
CoA

CAS #: 106-50-3 EC Number: 203-404-7 Molar Mass: 108.14 g/mol Hill Formula: C₆H₈N₂

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Overview

Key Spec Table

CAS #	EC Number	Hill Formula	Molar Mass
106-50-3	203-404-7	C₆H₈N₂	108.14 g/mol

Pricing & Availability

Catalogue Number	Availability	Packaging	Qty/Pack	Price	Quantity
8072460005	— Contact Customer Service	Glass bottle	5 g	Upon Order Completion More Information	—	Add To Favorites
8072460250	— Contact Customer Service	Glass bottle	250 g	Upon Order Completion More Information	—	Add To Favorites
8072461000	— Contact Customer Service	Glass bottle	1 kg	Upon Order Completion More Information	—	Add To Favorites
8072469025	— Contact Customer Service	Plastic drum	25 kg	Upon Order Completion More Information	—	Add To Favorites

Description
Catalogue Number	807246

Product Information
CAS number	106-50-3
EC index number	612-028-00-6
EC number	203-404-7
Hill Formula	C₆H₈N₂
Molar Mass	108.14 g/mol
HS Code	2921 51 19
Structure formula Image
Quality Level	MQ200

Applications
Application	1,4-Phenylenediamine for synthesis. CAS 106-50-3, pH 9 (50 g/l, H₂O, 20 °C).

Physicochemical Information
Boiling point	267 °C (1013 hPa)
Density	1.135 g/cm3 (20 °C)
Flash point	156 °C
Ignition temperature	567 °C
Melting Point	139 – 141 °C
pH value	9 (50 g/l, H₂O, 20 °C)
Vapor pressure	0.01 hPa (20 °C)
Bulk density	600 kg/m3
Solubility	47 g/l

Toxicological Information
LD 50 oral	LD50 Rat 80 mg/kg
LD 50 dermal	LD50 Rabbit > 7940 mg/kg

Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s)	H331: Toxic if inhaled. H311: Toxic in contact with skin. H301: Toxic if swallowed. H319: Causes serious eye irritation. H317: May cause an allergic skin reaction. H410: Very toxic to aquatic life with long lasting effects.
Precautionary Statement(s)	P280: Wear protective gloves. P273: Avoid release to the environment. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Signal Word	Danger
RTECS	SS8050000
Storage class	6.1C Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK	WGK 3 highly hazardous to water

Safety Information
Hazard Symbols	Dangerous for the environment Toxic
Categories of danger	toxic, irritant, sensitizing, dangerous for the environment
R Phrase	R 23/24/25-36-43-50/53 Toxic by inhalation, in contact with skin and if swallowed.Irritating to eyes.May cause sensitisation by skin contact.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase	S 28-36/37-45-60-61 After contact with skin, wash immediately with plenty of soap and water.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste.Avoid release to the environment. Refer to special instructions/ Safety data sheets.

Storage and Shipping Information
Storage	Store below +30°C.

Transport Information
Declaration (railroad and road) ADR, RID	UN 1673 , 6.1, III
Declaration (transport by air) IATA-DGR	UN 1673 , 6.1, III
Declaration (transport by sea) IMDG-Code	UN 1673 , 6.1, III

Specifications
Assay (GC, area%)	≥ 98.0 % (a/a)
Identity (IR)	passes test

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